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Abstract The East Asian summer monsoon (EASM) supplies vital rainfall for over one billion people. El Niño-Southern Oscillation (ENSO) markedly affects the EASM, but its impacts are more robust following El Niño than La Niña. Here, we show that this asymmetry arises from the asymmetry in ENSO evolution: though most El Niño events last for one year, La Niña events often persist for 2-3 years. In the summers between consecutive La Niña events, the concurrent La Niña opposes the delayed effect of the preceding winter La Niña on the EASM, causing a reduction in the magnitude and coherence of climate anomalies. Results from a large ensemble climate model experiment corroborate and strengthen the observational analysis with an order of magnitude increase in sample size. The apparent asymmetry in the impacts of the ENSO on the EASM can be reduced by considering the concurrent ENSO, in addition to the ENSO state in the preceding winter. This has important implications for seasonal climate forecasts. 

Abstract The influence of El Niño–Southern Oscillation (ENSO) in the Asian monsoon region can persist through the post-ENSO summer, after the sea surface temperature (SST) anomalies in the tropical Pacific have dissipated. The long persistence of coherent post-ENSO anomalies is caused by a positive feedback due to interbasin ocean–atmospheric coupling, known as the Indo-western Pacific Ocean capacitor (IPOC) effect, although the feedback mechanism itself does not necessarily rely on the antecedence of ENSO events, suggesting the potential for substantial internal variability independent of ENSO. To investigate the respective role of ENSO forcing and non-ENSO internal variability, we conduct ensemble “forecast” experiments with a full-physics, globally coupled atmosphere–ocean model initialized from a multidecadal tropical Pacific pacemaker simulation. The leading mode of internal variability as represented by the forecast-ensemble spread resembles the post-ENSO IPOC, despite the absence of antecedent ENSO forcing by design. The persistent atmospheric and oceanic anomalies in the leading mode highlight the positive feedback mechanism in the internal variability. The large sample size afforded by the ensemble spread allows us to identify robust non-ENSO precursors of summer IPOC variability, including a cool SST patch over the tropical northwestern Pacific, a warming patch in the tropical North Atlantic, and downwelling oceanic Rossby waves in the tropical Indian Ocean south of the equator. The pathways by which the precursors develop into the summer IPOC mode and the implications for improved predictability are discussed. 

Nature has long been a dominant source of inspiration in the area of chemistry, serving as prototypes for the design of materials with proficient performance. In this Feature article, we present our efforts to explore porous organic polymers (POPs) as a platform for the construction of biomimetic materials to enable new technologies to achieve efficient conversions and molecular recognition. For each aspect, we first present the chemical basis of nature, followed by depicting the principles and design strategies involved for functionalizing POPs along with a summary of critical requirements for materials, culminating in a demonstration of unique features of POPs. Our endeavours in using POPs to address the fundamental scientific problems related to biomimetic catalysis and adsorption are then illustrated to show their enormous potential and capabilities for applications ranging from concerted catalysis to radionuclide sequestration. To conclude, we present a personal perspective on the challenges and opportunities in this emerging field.